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Assessment of the metal contamination evolution in the Loire estuary using Cu and Zn stable isotopes and geochemical data in sediments ArchiMer
Ferreira Araujo, Daniel; Ponzevera, Emmanuel; Briant, Nicolas; Knoery, Joel; Sireau, Teddy; Mojtahid, Meryem; Metzger, Edouard; Brach-papa, Christophe.
In this work, a multi-elemental approach combining Cu and Zn stable isotopes is used to assess the metal contamination evolution in the Loire estuary bulk sediments. Elemental geochemical data indicate an increase of metal concentrations from the beginning of the industrial period peaking in the 1990s, followed by an attenuation of metal contamination inputs to the estuary. Zinc isotope compositions suggest a binary mixing process between Zn derived from terrigenous material and multi-urban anthropogenic sources. Copper isotope systematics indicate a single natural dominant source represented by weathered silicate particles from soils and rocks. This work demonstrates the applicability of Zn isotopes to identify anthropogenic Zn sources in coastal systems,...
Tipo: Text Palavras-chave: Coastal pollution; Coastal biogeochemistry; Geochemical tracers; Metal isotopes; Trace metal; Anthropogenic contamination.
Ano: 2019 URL: https://archimer.ifremer.fr/doc/00490/60188/67760.pdf
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